Publication | Closed Access
An Improved Reaction of <i>tris</i>(Methylthio) methane with Epoxides: Application to the Efficient Synthesis of β-Hydroxy Esters
14
Citations
5
References
1993
Year
Chemical EngineeringEngineeringBiochemistryImproved ReactionNatural SciencesCatalytic SynthesisAbstract TrisOrganic ChemistryOrganometallic CatalysisCatalysisEfficient SynthesisChemistryHigh Yieldβ-Hydroxy EstersSynthetic ChemistryBiomolecular Engineering
Abstract Tris(methylthio) methyllithium reacts efficiently with epoxides in THF:HMPA (5:1) at low temperature to give β-hydroxy orthotrithiocarboxylates which are converted to β-hydroxy esters in high yield.
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