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LiClO4-Catalyzed Ring-Opening of Aziridines with Aromatic Amines
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2002
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HalogenationEngineeringCatalytic AmountHeterocyclicAromatic AminesOrganic ChemistryLiclo4-catalyzed Ring-openingOrganometallic CatalysisChemistryHeterocycle ChemistryLithium PerchlorateEnantioselective SynthesisBiomolecular Engineering
A variety of N-tosylaziridines undergo smoothly ring opening with aromatic amines using a catalytic amount of lithium perchlorate in acetonitrile at ambient temperature to afford the corresponding 1,2-diamines in excellent yields.