Palladium-Catalyzed Hetero-Cope Rearrangement of Alkyl Allyl<i>N</i>-Aryldithiocarbonimidates

Abstract

Palladium-catalyzed [3,3] sigmatropic rearrangement of allyl methyl N-aryldithiocarbonimidates affords methyl N-allyl-N-aryldithiocarbamates. Very high yields of rearranged products can be obtained depending on the substitution pattern of the allyl group.