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Planar and Central Chiral [2.2]Paracyclophanes as Powerful Catalysts for Asymmetric 1,2-Addition Reactions
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2004
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Chemical EngineeringCross-coupling ReactionEngineeringHeterocyclicAryl Zinc ReagentsOrganic ChemistryPowerful CatalystsAsymmetric 1,2-Addition ReactionsCatalysisEnantioselective AdditionChemistryOrganometallic CatalysisAsymmetric CatalysisEnantioselective SynthesisBiomolecular Engineering
Planar and central chiral [2.2]paracyclophane ligands have been designed and used in the highly enantioselective addition of alkyl, alkenyl, alkynyl and aryl zinc reagents to aldehydes and imines.