Publication | Closed Access
A Flexible Synthesis of the Phytoprostanes B<sub>1</sub> Type I and II
56
Citations
5
References
2005
Year
Asymmetric CatalysisBiosynthesisEngineeringBiochemistryNatural SciencesDiversity-oriented SynthesisChiral Phosphonium SaltsNatural Product BiosynthesisOrganic ChemistryStereoselective SynthesisChemistryPhytochemistryNatural Product SynthesisFlexible SynthesisSynthetic ChemistryEnantioselective SynthesisBiomolecular EngineeringKey Steps
Syntheses of the enantiomerically pure phytoprostanes B(1) type I and II are described starting from furfural and n-propylfuran. Key steps include the preparation of the Freimanis (+/-)-hydroxycyclopentenone and Wittig coupling using chiral phosphonium salts.
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