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[Mo<sup>V</sup><sub>12</sub>O<sub>30</sub>(μ<sub>2</sub>-OH)<sub>10</sub>H<sub>2</sub>{Ni<sup>II</sup>(H<sub>2</sub>O)<sub>3</sub>}<sub>4</sub>], a Highly Symmetrical <i>ε</i>-Keggin Unit Capped with Four Ni<sup>II</sup> Centers: Synthesis and Magnetism
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2000
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Magnetic PropertiesEngineeringMagnetic ResonanceMolecular BiologyChemistryElectronic StructureNovel Title CompoundInorganic CompoundMagnetismSpin TopologiesQuantum MaterialsTd SymmetryInorganic ChemistrySpin-charge-orbit ConversionPhysicsSolid-state PhysicInorganic SynthesisSpintronicsMolecule-based MagnetNatural SciencesApplied PhysicsCondensed Matter Physics
The novel title compound {NiII4MoV12} demonstrates the concept of generating targeted spin topologies using reduced polyoxometalates: The four electrophilic nickel centersforming a tetrahedronare fixed by a nucleophilic highly reduced diamagnetic ε-Keggin cluster of Td symmetry generated in solution. This cluster not only has a structural role but actually participates in the transmission of the exchange interaction.
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