Phosphine-free Suzuki cross-coupling reactions under ultrasound

A convenient synthesis of acetylenes: catalytic substitutions of acetylenic hydrogen with bromoalkenes, iodoarenes and bromopyridines

Kenkichi Sonogashira, Yasuo Tohda, Nobue Hagihara · Tetrahedron Letters · 1975 · 5.1K citations

Chemical Engineering, Catalytic Substitutions, Engineering +8

The Palladium‐Catalyzed Cross‐Coupling Reactions of Organotin Reagents with Organic Electrophiles [New Synthetic Methods (58)]

J. K. Stille · Angewandte Chemie International Edition in English · 1986 · 3.4K citations

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Palladium‐Catalyzed Cross‐Coupling Reactions in Total Synthesis

K. C. Nicolaou, Paul G. Bulger, David Šarlah · Angewandte Chemie International Edition · 2005 · 2.7K citations

Chemical Engineering, New Family, Engineering +9

Palladium-catalyzed vinylic hydrogen substitution reactions with aryl, benzyl, and styryl halides

Richard F. Heck, J. P. Nolley · The Journal of Organic Chemistry · 1972 · 2.1K citations

Chemical Engineering, Cross-coupling Reaction, Engineering +12

The Palladium-Catalyzed Cross-Coupling Reaction of Phenylboronic Acid with Haloarenes in the Presence of Bases

Norio Miyaura, Teiji Yanagi, Atsushi Suzuki · Synthetic Communications · 1981 · 1.9K citations · Full text

Transition Metal-catalyzed Reactions, Chemical Engineering, Cross-coupling Reaction +11