Zeitschrift für anorganische und allgemeine Chemie · 1980 · 20 citations · 10 references
Natural SciencesMaterials EngineeringMaterials ScienceInorganic ChemistryPhysical ChemistrySolid-state ChemistryConductive MaterialsCrystal ChemistryElectrical CharacterizationElectrical ConductivityMetal SulfidesMetalsChemical Transport ModelingConductivity MeasurementCrystal Chemistry Of SulfidesCrystal Structure Of SulfidesElectrical Conductivity MeasurementsElectrical Conductivity Of SulfidesEquilibriumIsotherms
Abstract An equilibrium isotherm on V‐S system at 900°C was determined by changing partial pressure of sulfur. Single crystals of several V 5 S 8 and V 2 S 3 compounds were grown by chemical transport. The grown crystals almost satisfied compositional relation on equilibrium isotherms between 900°C (hot zone) and lower temperatures (cold zone). Electrical conductivity of the single crystals was measured at temperatures from liquid nitrogen to 25°C. It showed metallic behavior without any significant dependence on compositional variation. Also the conductivity measurement of sintered samples for various vanadium sulfides was carried out in the compositional range from VS 1,38 (V 3 S 4 phase) to VS 1,58 (V 5 S 8 phase).
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The structures of the chromium sulphides
F. Jellinek · Acta Crystallographica · 1957 · 303 citations · Full text
Crystal structures of V3S4 and V5S8
I. Kawada, M. Nakano-Onoda, Motohiko Ishii et al. · Journal of Solid State Chemistry · 1975 · 97 citations