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Intramolecular Heck Cyclisation-β-Alkoxy Elimination in Carbohydrate Chemistry. A Simple Route to Enantiopure Annelated Dioxatricyclic Compounds
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1999
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EngineeringBiochemistryNatural SciencesIntramolecular Heck CyclizationPalladium-β-alkoxy EliminationEnantiopure Cis-fused PyranoOrganic ChemistryA Simple RouteStereoselective SynthesisChemistryHeterocycle ChemistryPharmacologyAsymmetric CatalysisEnantioselective SynthesisBiomolecular EngineeringNatural Product Synthesis
Enantiopure cis-fused pyrano[2,3c]pyrans are obtained from glycals via an intramolecular Heck cyclization followed by a palladium-β-alkoxy elimination.