Publication | Closed Access
Oxidizing Polymers: A Polymer-Supported, Recyclable Hypervalent Iodine(V) Reagent for the Efficient Conversion of Alcohols, Carbonyl Compounds, and Unsaturated Carbamates in Solution J.R. gratefully acknowledges generous support from Prof. M. E. Maier, Tübingen, the Strukturfonds of the University of Tübingen, the Fonds der Chemischen Industrie, and the DFG. We thank Graeme Nicholson, Dietmar Schmid, and Daniel Bischoff for analytical support.
139
Citations
0
References
2001
Year
Organic Material ChemistryChemical EngineeringVarious AlcoholsEngineeringNovel OrganocatalystsGraeme NicholsonOrganic ChemistryAmino AlcoholsSynthetic ChemistryAnalytical SupportChemistryRecyclable Hypervalent IodinePolymer ReactionComplex AlcoholsPolymer ChemistryPolymer SynthesisPolymers
The oxidation of various alcohols and cyclization of an olefinic carbamate succeeds with the first polymer-supported iodine(V) reagent (see scheme). The novel oxidizing polymer oxidizes sensitive and complex alcohols, including protected amino alcohols, efficiently in good to excellent yields. In addition, the α,β-dehydration of a ketone is demonstrated.