A Convenient Synthesis of 2-Alkylated 1,4-Benzenediols - Concepedia

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A Convenient Synthesis of 2-Alkylated 1,4-Benzenediols

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1997

Year

Y. OZAKI, Ayako Hosoya, K. OKAMURA, Sangwon Kim

EngineeringHeterocyclicAlkene MetathesisMetal HalidesOrganic ChemistryCatalysisChemistry2-Alkylated 1,4-BenzenediolsSynthetic ChemistryEnantioselective SynthesisGood Yields

Abstract

Reaction of 1,4-cyclohexanedione with a variety of aldehydes in the presence of metal halides generated the 2-alkylated 1,4-benzenediols in good yields without any aromatic by-products.