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Pd-Catalyzed Asymmetric Allylic Amination Using Aspartic Acid Derived P-Chirogenic Diaminophosphine Oxides: DIAPHOXs
52
Citations
18
References
2005
Year
Cross-coupling ReactionEngineeringChiral Allylic AminesOrganic ChemistryCatalysisCyclic SubstratesChemistryAsymmetric CatalysisAsymmetric Allylic AminationSynthetic ChemistryEnantioselective SynthesisBiomolecular Engineering
A Pd-catalyzed asymmetric allylic amination using aspartic acid derived P-chirogenic diaminophosphine oxides (DIAPHOXs) is described. Asymmetric allylic amination of both linear and cyclic substrates proceeded at room temperature to give the chiral allylic amines in 72−99% ee.
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