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Iodine/Triethylsilane as a Convenient Promoter System for the Activation of Disarmed Glycosyl Trichloro- and N-(Phenyl)trifluoroacetimidates
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2002
Year
EngineeringBiochemistryConvenient Promoter SystemNatural SciencesGlycobiologyChemical DerivativeMolecular BiologyOrganic ChemistryReagent System I2/et3sihSecondary Saccharidic AcceptorsHalogenationDisarmed Glycosyl Trichloro-Synthetic ChemistryBiomolecular EngineeringGlycosylation
Disarmed glycosyl trichoro- and N-(phenyl)trifluoroacetimidates can be efficiently activated by the combined reagent system I2/Et3SiH in the fast and high yielding glycosylation of primary and secondary saccharidic acceptors.