Publication | Closed Access
Ln[N(SiMe<sub>3</sub>)<sub>2</sub>]<sub>3</sub>/RNH<sub>2</sub> Catalyzed Monoaddition of Terminal Alkynes to Nitriles: A Novel and Concise Access to the Synthesis of Ynones
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Citations
56
References
2008
Year
Terminal AlkynesCross-coupling ReactionEngineeringMild MethodConjugated YnonesOrganometallic CatalysisCatalysisConcise AccessChemistryAsymmetric CatalysisSynthetic ChemistryEnantioselective SynthesisBiomolecular Engineering
A mild and highly selective Ln[N(SiMe3)2]3/n-BuNH2 catalyzed addition of terminal alkynes to nitriles has been established, revealing a novel reactivity pattern of alkynes with nitriles and providing a new, economical, and mild method for the synthesis of conjugated ynones.
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