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Ubiquitous Benzoquinones, Multitalented Compounds for Palladium‐Catalyzed Oxidative Reactions
64
Citations
84
References
2015
Year
Chemical EngineeringEngineeringOrganic ChemistryAbstract PalladiumOrganometallic CatalysisCatalysisPd IiChemistryMolecular CatalysisUbiquitous BenzoquinonesPersonal ObservationsCatalytic Synthesis
Abstract Palladium(II)‐catalyzed procedures often use benzoquinone (BQ) to regenerate the catalyst. Besides its oxidation role, BQ can also promote various steps of the catalytic cycle. This review highlights the multifaceted properties of BQ and its analogues when involved in Pd II ‐catalyzed oxidative reactions and presents mechanisms proposed in the literature, in some cases with personal observations.
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