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Efficient Palladium-Catalysed Enamide Synthesis from Enol Triflates and Enol Tosylates
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2005
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Cross-coupling ReactionEngineeringUnactivated Vinyl TriflatesExcellent YieldsCatalytic SynthesisOrganic ChemistryOrganometallic CatalysisCatalysisEnol TriflatesChemistrySynthesis MethodAsymmetric CatalysisEnantioselective SynthesisBiomolecular Engineering
Catalysts generated from Pd2(dba)3 and biphenyl ligands 4 and 7 efficiently promote the coupling of amides and carbamates with unactivated vinyl triflates and tosylates, to provide enamides in good to excellent yields.