Concepedia

A Convenient Preparation of 2,4,6-Trisubstituted 1,3,5-Triselenanes by Treating Aldehydes or Their Acetals with 2,2,4,4,6,6-Hexamethyl-1,3,5-triselena-2,4,6-tristannacyclohexane in the Presence of BF3·OEt2 and AlCl3

Kazuaki Shimada, Satoshi Okuse, Yuji Takikawa

Bulletin of the Chemical Society of Japan · 1992 · 12 citations · 4 references

DOI

Concepts

Abstract

Abstract A convenient preparation of 2,4,6-trisubstituted 1,3,5-triselenanes was achieved by the treatment of aldehydes or their acetals with 2,2,4,4,6,6-hexamethyl-1,3,5-triselena-2,4,6-tristannacyclohexane, (Me2SnSe)3, in the presence of BF3·OEt2 and AlCl3.

References

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Novel synthesis of 1,3,5-triselenanes from aldehydes, and novel generation of selenoaldehydes by fragmentation of 1,3,5-triselenanes

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