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Formal Total Synthesis of Ovalcin by Carbohydrate Approach
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2007
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Bioorganic ChemistryEngineeringCarbohydrate ApproachBiochemistryKey StepsNatural SciencesAlkene MetathesisSynthetic BiologyFormal Total SynthesisStereoselective SynthesisSynthesis MethodNatural Product SynthesisSynthetic ChemistryEnantioselective SynthesisBiomolecular EngineeringAvailable Sugar Ribose
A formal total synthesis of ovalcin is described herein starting from readily available sugar ribose with selective zinc-mediated ring-opening reaction and Grubbs olefin metathesis as the key steps.