Stable Ligand Coordination at the Surface of Colloidal CsPbBr₃ Nanocrystals

Abstract

Ruling over the surface chemistry of metal halide perovskite nanocrystals (NCs) is crucial to access reliable luminophores. Here, we provide an atomic-level description of the surface of colloidal CsPbBr₃ NCs, achieving an effective passivation strategy that leads to near-unity photoluminescence quantum yield. To this end, we used two different types of CsPbBr₃ NCs, which had been synthesized with an outer shell of either oleylammonium bromide ion pairs or Cs-oleate complexes. We perturbed the dynamic equilibria at the NCs' surface with ligands from a comprehensive library, including amines (and their conjugated acids) with different basicities, chain lengths, and steric encumbrances. We demonstrate that control of both ligand binding affinity and ligand-to-NC molar ratio is essential to attain thermodynamically stable coordination of the NC surface. We thus present a reliable protocol for managing the surface chemistry of colloidal CsPbBr₃ NCs and for selectively addressing their ligand-induced morphological (and structural) transformations.