Publication | Closed Access
Synthesis of C<sub>25</sub>- and C<sub>26</sub>-Steroid Carboxylic Acids from C<sub>22</sub>-Steroids Using Nickelacycles as Propionic and Butyric Acid Equivalents
16
Citations
0
References
1993
Year
Butyric Acid EquivalentsEngineeringHeterocyclicBiochemistryNatural SciencesDiversity-oriented SynthesisMethyl EstersOrganic ChemistryOrganometallic CatalysisCatalysisStereoselective SynthesisChemistryNatural Product SynthesisSynthetic ChemistryBiomolecular EngineeringNickelacycles 2A
C25- and C26 -steroid carboxylic acids as well as their methyl esters with different rings A and B were synthesized with good to excellent yields from C22 -iodides 1 using the nickelacycles 2a and 2b as propionic and butyric acid equivalents.