Concepedia

Synthesis of Spiroannulated Dihydrofurans by Cerium(IV) Ammonium Nitrate Mediated Addition Of 1,3-Dicarbonyl Compounds to Exocyclic Alkenes

Vijay Nair, Jessy Mathew, S Shashkov Alexander

Synthetic Communications · 1995 · 31 citations · 25 references

DOI

Concepts

Abstract

Abstract Cerium (IV) ammonium nitrate (CAN) mediated addition of 1, 3-dicarbonyl compounds to exocyclic alkenes occurs smoothly at 5°C in methanol to afford spiroannulated dihydrofurans in moderate to good yields.

References

25

Manganese(III) Mediated Reactions of Unsaturated Systems

Gagik G. Melikyan · Synthesis · 1993 · 189 citations

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Oxidation reactions of manganese(III) acetate. II. Formation of .gamma.-lactones from olefins and acetic acid

John B. Bush, Herman Finkbeiner · Journal of the American Chemical Society · 1968 · 174 citations

, , +8

Oxidation by metal salts. IV. A new method for the preparation of .gamma.-lactones by the reaction of manganic acetate with olefins

El-Ahmadi I. Heiba, Ralph M. Dessau, William J. Koehl · Journal of the American Chemical Society · 1968 · 168 citations

, , +6

Oxidation by metal salts. X. One-step synthesis of .gamma.-lactones from olefins

El-Ahmadi I. Heiba, Ralph M. Dessau, Paul G. Rodewald · Journal of the American Chemical Society · 1974 · 158 citations

, , +6

A new and general synthesis of polycyclic .gamma.-lactones by double annulation

E. J. Corey, Myung Chol Kang · Journal of the American Chemical Society · 1984 · 149 citations

, , +5