Concepedia

Allylic Phosphinates via Palladium-Catalyzed Allylation of <i>H-</i>Phosphinic Acids with Allylic Alcohols

Laëtitia Coudray, Karla Bravo‐Altamirano, Jean‐Luc Montchamp

Organic Letters · 2008 · 56 citations · 27 references

Concepts

Novel Catalytic AllylationPalladium-catalyzed AllylationEngineeringCross-coupling ReactionBiochemistryH-phosphinic AcidsNatural SciencesCatalytic SynthesisAllylic AlcoholsAllylic PhosphinatesOrganic ChemistryCatalysisMolecular CatalysisChemistryAsymmetric CatalysisSynthetic ChemistryBiomolecular Engineering

Abstract

A novel catalytic allylation of H-phosphinic acids is described. Using Pd/xantphos (2 mol %), H-phosphinic acids react directly with allylic alcohols to produce P-allylated disubstituted phosphinic acids.

References

27

A Versatile and Efficient Ligand for Copper‐Catalyzed Formation of CN, CO, and PC Bonds: Pyrrolidine‐2‐Phosphonic Acid Phenyl Monoester

Honghua Rao, Ying Jin, Hua Fu et al. · Chemistry - A European Journal · 2006 · 367 citations

Efficient and Selective Nickel-Catalyzed Addition of H−P(O) and H−S Bonds to Alkynes

Li‐Biao Han, Chen Zhang, Hideaki Yazawa et al. · Journal of the American Chemical Society · 2004 · 250 citations

Chemical Engineering, H−s Bonds, Cheap Nickel Catalysts +10

Triethylborane-Initiated Room Temperature Radical Addition of Hypophosphites to Olefins: Synthesis of Monosubstituted Phosphinic Acids and Esters

Sylvine Deprèle, Jean‐Luc Montchamp · The Journal of Organic Chemistry · 2001 · 155 citations

Room Temperature, Engineering, Alkene Metathesis +12

Proline/Pipecolinic Acid-Promoted Copper-Catalyzed <i>P</i>-Arylation

Cheng Huang, Xu Tang, Hua Fu et al. · The Journal of Organic Chemistry · 2006 · 155 citations

Copper-catalyzed addition of H-phosphine oxides to alkynes forming alkenylphosphine oxides

Mingyu Niu, Hua Fu, Yuyang Jiang et al. · Chemical Communications · 2006 · 135 citations