Journal of Coordination Chemistry · 1993 · 33 citations · 31 references
Natural SciencesChemistryMedicinal ChemistryOrganic ChemistryAmino Acid ChemistryAmino AcidsStereochemistry Of Amino AcidsSteric Constraints
Abstract Reaction of aluminum alkyls with primary or secondary amines readily affords dimeric or trimeric aminoalanes. Steric constraints of the substituents on aluminum and nitrogen substantially affect the structural nature of the products. Ring size, conformational data, and structural trends are reported for a number of dimeric and trimeric aminoalanes.
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