Pd(II)-Catalyzed Direct Olefination of Arenes with Allylic Esters and Ethers - Concepedia

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Pd(II)-Catalyzed Direct Olefination of Arenes with Allylic Esters and Ethers

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2012

Year

Zhong‐Quan Liu, Xiaojie Shang, Yun Xiong, Yuexia Zhang, Lei Zhang

Chemical EngineeringEngineeringAllylic EstersAlkene MetathesisOrganic ChemistryOrganometallic CatalysisCatalysisChemistryDirect OlefinationAsymmetric CatalysisCatalytic SynthesisConvenient Pd

Abstract

A convenient Pd(II)-catalyzed direct olefination of unactivated arenes with allylic esters and ethers via C-H activation was demonstrated. Under the typical conditions, various aryl-substituted allylic esters and ethers can be prepared.