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Layered K<sub>4</sub>[Re<sub>6</sub>S<sub>10</sub>(CN)<sub>2</sub>] and Chainlike K<sub>4</sub>[Re<sub>6</sub>Se<sub>10</sub>(CN)<sub>4</sub>]: New Types of Chalcocyanide Cluster Compounds with Bridging Chalcogenide Ligands
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Citations
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References
2000
Year
Materials ScienceInorganic ChemistryTerminal Cn- LigandsEngineeringCoordination ComplexBridging Chalcogenide LigandsChalcocyanide Cluster CompoundsNew TypesHigh TemperaturesMain Group ChemistryChemistryInorganic SynthesisChalcogenido LigandsInorganic Compound
The chalcocyanide compounds K4[Re6S10(CN)2] (1) and K4[Re6Se10(CN)4] (2) have been synthesized from ReQ2 (Q = S, Se) and molten KCN at high temperatures and characterized by single-crystal X-ray diffraction methods. Both compounds exhibit bridging chalcogenido ligands between [Re6Q8]2+ cores and terminal CN- ligands.
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