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Regio- and Enantioselective Ring-Opening of Epoxides with HMDST: A Straightforward Access to 1,2-Mercaptoalcohols
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2005
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Asymmetric CatalysisEnantioselective SynthesisEngineeringAlkene MetathesisBiochemistryNatural SciencesStraightforward AccessOrganic ChemistryCatalysisSubstituted EpoxidesChemistryTbaf-catalyzed ReactionSimple AccessNatural Product SynthesisStereoselective SynthesisSynthetic ChemistryEnantioselective Ring-openingBiomolecular Engineering
TBAF-catalyzed reaction of a range of substituted epoxides with hexamethyldisilathiane smoothly affords a direct and simple access to β-mercaptoalcohols in a highly regio- and stereoselective way.