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Facile One-pot Syntheses of Amidines and Enamines from Oximes via Beckmann Rearrangement Using Trifluoromethansulfonic Anhydride
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Citations
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References
2004
Year
EngineeringMild ConditionsOrganic ChemistrySynthetic ChemistryStereoselective SynthesisChemistryNatural Product SynthesisBeckmann RearrangementOne-pot SynthesesEnantioselective SynthesisBiomolecular EngineeringCarbocation Intermediates
Abstract Facile one-pot syntheses of amidines and enamines were achieved by trapping carbocation intermediates that were formed by Beckmann rearrangement of oximes with amines and carbon nucleophiles, respectively, under mild conditions.
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