Concepedia

Bicyclic P<sub>6</sub> as Complex Ligand

Otto J. Scherer, Bernd Werner, Gert Heckmann, Gotthelf Wolmershäuser

Angewandte Chemie International Edition in English · 1991 · 56 citations · 10 references

DOI

Concepts

Abstract

The binuclear Th complex 1 contains a new type of P6 ligand, which is derived formally from P6 benzvalene. Amber-colored, extremely air-sensitive crystals of 1 are formed on cothermolysis of the butadiene complex [Cp2Th(η4-C4H6] and P4 in toluene.

References

10

Complexes with Substituent‐free Acyclic and Cyclic Phosphorus, Arsenic, Antimony, and Bismuth Ligands

Otto J. Scherer · Angewandte Chemie International Edition in English · 1990 · 276 citations

, , +15

The analytic configuration interaction gradient method: Application to the cyclic and open isomers of the S3 molecule

Julia E. Rice, Roger D. Amos, Nicholas C. Handy et al. · The Journal of Chemical Physics · 1986 · 251 citations

, , +13

Transition Metal Complexes with <i>cyclo</i>‐Triphosphorus (η<sup>3</sup>‐P<sub>3</sub>) and <i>tetrahedro</i>‐Tetraphosphorus (η<sup>1</sup>‐P<sub>4</sub>) Ligands

Massimo Di Vaira, Luigi Sacconi · Angewandte Chemie International Edition in English · 1982 · 120 citations

, , +12

An organothorium-nickel phosphido complex with a short thorium-nickel distance. The structure of Th(.eta.5-C5Me5)2(.mu.-PPh2)2Ni(CO)2

John M. Ritchey, A. J. Zozulin, Debra A. Wrobleski et al. · Journal of the American Chemical Society · 1985 · 82 citations

, , +6

Synthesis and x-ray structure of (C5Me5)2Th(.mu.-PPh2)2Pt(PMe3): a complex with a thorium-platinum bond

Phillipa Hay, R. R. Ryan, K.V. Salazar et al. · Journal of the American Chemical Society · 1986 · 81 citations

, , +14