An umpolung sulfoxide reagent for use as a functionalized benzyl carbanion equivalent

Methods of Reactivity Umpolung

Dieter Seebàch · Angewandte Chemie International Edition in English · 1979 · 1.2K citations

Natural Sciences, Chemistry, Green Chemistry +9

Nucleophilic Carbenes in Asymmetric Organocatalysis

Dieter Enders, Tim Balensiefer · Accounts of Chemical Research · 2004 · 1K citations

Natural Sciences, Biochemistry, Chemistry +14

Carbanions of 1,3‐Dithianes. Reagents for CC Bond Formation by Nucleophilic Displacement and Carbonyl Addition

E. J. Corey, D. Seebach · Angewandte Chemie International Edition in English · 1965 · 355 citations

Natural Sciences, Chemistry, Medicinal Chemistry +10

Evolution of Dithiane-Based Strategies for the Construction of Architecturally Complex Natural Products

Amos B. Smith, Christopher M. Adams · Accounts of Chemical Research · 2004 · 333 citations

Natural Sciences, Chemistry, Natural Product Biosynthesis +9

Umpolung reactivity in amide and peptide synthesis

Bo Shen, Dawn M. Makley, Jeffrey N. Johnston · Nature · 2010 · 313 citations

Natural Sciences, Chemistry, Medicinal Chemistry +13