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Microwave-Assisted Regiospecific Synthesis of Pseudohalohydrin Esters
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2012
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Asymmetric CatalysisMicrowave SynthesisEngineeringAlkene MetathesisOrganic ChemistryCatalysisHalohydrin Ester SurrogatesMicrowave-assisted Regiospecific SynthesisChemistryPalladium CatalysisN-acylbenzotriazoles ReactSynthetic ChemistryEnantioselective SynthesisBiomolecular Engineering
N-Acylbenzotriazoles react regiospecifically with epoxides under palladium catalysis to give novel β-(benzotriazol-1-yl)ethyl esters (52–87%) constituting halohydrin ester surrogates.