Concepedia

Mannich‐Type Reactions Catalyzed by Neutral Salts in Water

Catherine Loncaric, Kei Manabe, Shū Kobayashi

Advanced Synthesis & Catalysis · 2003 · 17 citations · 17 references

DOIFull text

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Concepts

Abstract

Abstract Mannich‐type reactions of imines with silicon enolates were found to be catalyzed by neutral salts such as sodium triflate in water as a suspension medium. Unusual kinetic behavior indicates that the presence of the Mannich adduct facilitates the rate of its formation.

References

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