Publication | Open Access
Propargylation of Aldehydes Using Potassium Allenyltrifluoroborate
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2014
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Room TemperatureChemical EngineeringNovel OrganocatalystsEngineeringAlkene MetathesisFluorous SynthesisOrganic ChemistryCatalysisSynthetic ChemistryChemistryPotassium AllenyltrifluoroborateShort Reaction TimesEnantioselective Synthesis
The commercially available resin Amberlyst A-31 was efficiently used to promote the propargylation of aldehydes using potassium allenyltrifluoroborate. The method is simple and fast, and the products were obtained in short reaction times in high yields and purity at room temperature in a regio- and chemoselective manner.