Synthesis and structure of diastereomers of pentenocin B produced by Trichoderma hamatum FO-6903

Synthesis of .alpha.,.beta.-unsaturated carbonyl compounds by palladium(II)-catalyzed dehydrosilylation of silyl enol ethers

Yoshihiko Ito, Toshikazu Hirao, Takeo Saegusa · The Journal of Organic Chemistry · 1978 · 861 citations

Natural Sciences, Chemistry, Catalysis +5

Organoaluminum reagents of type R1R2NAlEt2 which allow regiospecific isomerization of epoxides to allylic alcohols

Arata Yasuda, Shin Tanaka, Koichiro Oshima et al. · Journal of the American Chemical Society · 1974 · 133 citations

Natural Sciences, Chemistry, Green Chemistry +5

Generation of alkylidenecarbenes by the alkenation of carbonyl compounds with lithiotrimethylsilyldiazomethane

Susumu Ohira, Keiji Okai, Takanori Moritani · Journal of the Chemical Society Chemical Communications · 1992 · 113 citations

Natural Sciences, Chemistry, Organic Chemistry +8

Facile isomerization of oxiranes to allyl alcohols by mixed metal bases

Alessandro Mordini, Ezzedine Ben Rayana, Christian Margot et al. · Tetrahedron · 1990 · 93 citations

Natural Sciences, Chemistry, Catalysis +11

2,2,5-Trimethyl-1,3-dioxolane-4-carboxaldehyde as a chiral synthon: synthesis of the two enantiomers of methyl 2,3,6-trideoxy-.alpha.-L-threo-hex-2-enopyranoside, key intermediate in the synthesis of daunosamine, and of (+)- and (-)-rhodinose

Stefano De Servi · The Journal of Organic Chemistry · 1985 · 49 citations

Natural Sciences, Chemistry, Medicinal Chemistry +8