Synlett · 2001 · 94 citations · 0 references
Natural SciencesChemistryCatalysisOrganic ChemistryChiral SeparationHeterocyclic ChemistryHeterogeneous CatalysisEnantioselective CatalysisEnantioselective Synthesis
The first example of an enantioselective and diastereoselective catalytic nitro-Mannich reaction using a second-generation heterobimetallic complex has been developed. The corresponding nitro-Mannich products were obtained in up to 83% ee with a dr up to 7:1.