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Enantiocontrol in intramolecular cyclopropanation of diazoketones. Conformational control of metal carbene alignment

Asymmetric CatalysisConformational ControlEngineeringHeterocyclicMetal Carbene AlignmentOrganic ChemistryStereoselective SynthesisChemistryMolecular ModelingIntramolecular CyclopropanationEnantioselective SynthesisBiomolecular Engineering