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Phenylation of Alkenyl Triflates: Reaction with Tetrabutylammonium Difluorotriphenylstannate.
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1994
Year
Chemical EngineeringCross-coupling ReactionAlkenyl TriflatesEngineeringCorresponding Alkenylbenzenes 2Fluorous SynthesisAlkenyl Triflates 1Organic ChemistryOrganometallic CatalysisCatalysisChemistryHalogenationTetrabutylammonium Difluorotriphenylstannate
The reaction of alkenyl triflates 1 with tetrabutylammonium difluorotriphenylstannate catalyzed by Pd(PPh3)4 affords regio and stereospecifically the corresponding alkenylbenzenes 2 in excellent yields.