Preparation of <i>N</i>-Sulfonylimines Bearing Easily Removable Protecting Groups via the Hudson Reaction of Oximes with Sulfinyl Chlorides - Concepedia

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Preparation of <i>N</i>-Sulfonylimines Bearing Easily Removable Protecting Groups via the Hudson Reaction of Oximes with Sulfinyl Chlorides

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References

2001

Year

Gerald D. Artman, Alessandra Bartolozzi, Richard W. Franck, Steven M. Weinreb

Corresponding Sulfinyl ChlorideChemical EngineeringEngineeringHudson ReactionSulfinyl ChloridesOrganic ChemistryCleavable T-butylsulfonylCatalysisChemistryDesulfurizationNatural Product SynthesisSynthetic ChemistryBiomolecular Engineering

Abstract

N-Sulfonylimines which incorporate easily cleavable t-butylsulfonyl (Bus) and β-trimethylsilylethanesulfonyl (SES) groups on nitrogen can be readily synthesized from oximes and the corresponding sulfinyl chloride by the Hudson reaction.