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Regioselective Acylation of Carbohydrates with 1-Acyloxy-1<i>H</i>-benzotriazoles
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1991
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Asymmetric CatalysisEngineeringBiochemistryNatural SciencesBiocatalysisRepresentative Carbohydrate DerivativesRegioselective AcylationOrganic ChemistryCatalysisNatural Product SynthesisObserved High RegioselectivitySynthetic ChemistryBiomolecular EngineeringMild Reaction Conditions
Acylation of representative carbohydrate derivatives was accomplished with in situ generated 1-acyloxy-1H-benzotriazoles. The observed high regioselectivity, mild reaction conditions and convenient work-up make the presented one-pot procedure generally applicable and more advantageous than acylations with previously introduced reagents, including N-acylimidazoles.