Phosphorylated derivatives of 1‐morpholinocyclohexene and cyclohexanone

Abstract

Abstract Phosphorylation of a relatively simple enamine with phosphorus (III) halides was first exemplified by the behavior of 1‐morpholinocyclohexene. Novel types of functionalized P(III) derivatives have now been obtained and studied. The hydrolysis of (2‐morpholino‐1‐cyclohexenyl) tetraethyldiamidophosphazidoarenes was found to be accompanied by the migration of the triazene group from the phosphorus atom to the carbon atom of the cyclohexene ring.