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Asymmetric Synthesis of (+)- and (-)-Eptazocine via an Enzymatic Reaction
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1996
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Medicinal ChemistryBiosynthesisEngineeringBiochemistryNbs T RactWithlipase FsBiocatalysisNatural SciencesAsymmetric SynthesisPropyl AcetateOrganic ChemistryStereoselective SynthesisChemistryEnzymatic ModificationPharmacologyAsymmetric CatalysisSynthetic ChemistryEnantioselective Synthesis
nbs t ract -Starting from (R)-3-hydroxy-2-(p-methoxybenzyl)propyl acetate (R-(+)-4) prepared by enzymatic monoacetylation of 2-(p-meth-oxybenzy1)propane-l,3-diol(3) withlipase FS in the presence of vinyl