Concepedia

The experimental determination of Th(<scp>iv</scp>)/Th(<scp>iii</scp>) redox potentials in organometallic thorium complexes

Christopher J. Inman, F. Geoffrey N. Cloke

Dalton Transactions · 2019 · 28 citations · 23 references

DOI

Concepts

Abstract

Th<sup>IV</sup>/Th<sup>III</sup> reduction wave in the cyclic voltammogram of [Th(η-C<sub>5</sub>H<sub>3</sub>{SiMe<sub>3</sub>}<sub>2</sub>)<sub>3</sub>Cl].

References

23

Electron-transfer and f-d absorption bands of some lanthanide and actinide complexes and the standard (II-III) oxidation potential for each member of the lanthanide and actinide series

L. J. Nugent, R.D. Baybarz, J. Burnett et al. · The Journal of Physical Chemistry · 1973 · 314 citations

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Trends in Electronic Structure and Redox Energetics for Early-Actinide Pentamethylcyclopentadienyl Complexes

David E. Morris, R.E. Da Re, K.C. Jantunen et al. · Organometallics · 2004 · 151 citations

, , +16

Actinide covalency measured by pulsed electron paramagnetic resonance spectroscopy

Alasdair Formanuik, Ana-Maria Ariciu, Fabrizio Ortu et al. · Nature Chemistry · 2016 · 136 citations · Full text

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Importance of Energy Level Matching for Bonding in Th<sup>3+</sup>-Am<sup>3+</sup> Actinide Metallocene Amidinates, (C<sub>5</sub>Me<sub>5</sub>)<sub>2</sub>[<sup>i</sup>PrNC(Me)N<sup>i</sup>Pr]An

Justin R. Walensky, Richard L. Martin, Joseph W. Ziller et al. · Inorganic Chemistry · 2010 · 120 citations

, , +17

Synthesis and Characterization of the First Sandwich Complex of Trivalent Thorium:  A Structural Comparison with the Uranium Analogue

Julian S. Parry, Cloke, Simon J. Coles et al. · Journal of the American Chemical Society · 1999 · 117 citations · Full text

, , +16