Concepedia

Green synthesis of benzonitrile using ionic liquid with multiple roles as the recycling agent

Zhihui Li, Tingting Wang, Xudong Qi, Qiusheng Yang, Liya Gao, Dongsheng Zhang, Xinqiang Zhao, Yanji Wang

RSC Advances · 2019 · 20 citations · 26 references

DOIFull text

Open access

Concepts

Abstract

was 2 : 1, the benzaldehyde conversion and benzonitrile yield were both 100% at 120 °C in 2 h. Even better, the ionic liquid could be recovered easily by phase separation, and recycled directly after reaction. Additionally, this novel route is applicable to the green synthesis of a variety of aromatic, heteroaromatic and aliphatic nitriles with excellent yields.

References

26

Potassium hexacyanoferrate(<scp>ii</scp>)—a new cyanating agent for the palladium-catalyzed cyanation of aryl halides

Thomas Schareina, Alexander Zapf, Matthias Beller · Chemical Communications · 2004 · 344 citations

, , +16

Palladium-Catalyzed Cyanation of Aryl Bromides Promoted by Low-Level Organotin Compounds

Chunhua Yang, J. Michael Williams · Organic Letters · 2004 · 172 citations

, , +8

Thermal decomposition of poly(propylene carbonate): End-capping, additives, and solvent effects

Oluwadamilola Phillips, Jared Schwartz, Paul A. Kohl · Polymer Degradation and Stability · 2016 · 93 citations

, , +16

Ultrasound-promoted synthesis of oximes catalyzed by a basic ionic liquid [bmIm]OH

Hong‐Jun Zang, Meiling Wang, Bowen Cheng et al. · Ultrasonics Sonochemistry · 2008 · 83 citations

, , +10

Stable and reusable nanoscale Fe<sub>2</sub>O<sub>3</sub>-catalyzed aerobic oxidation process for the selective synthesis of nitriles and primary amides

Kathiravan Murugesan, Thirusangumurugan Senthamarai, Manzar Sohail et al. · Green Chemistry · 2017 · 60 citations

, , +17