Concepedia

Selective C–F bond carboxylation of <i>gem</i>-difluoroalkenes with CO<sub>2</sub> by photoredox/palladium dual catalysis

Chuan Zhu, Yufeng Zhang, Ze‐Yao Liu, Lu Zhou, Haidong Liu, Chao Feng

Chemical Science · 2019 · 126 citations · 66 references

DOIFull text

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Concepts

Abstract

A catalytic C(sp<sup>2</sup>)–F bond carboxylation with CO<sub>2</sub> is reported; the reaction is enabled by dual photoredox/palladium catalysis and involves a crucial fluoroalkenyl radical intermediate.

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