Concepedia

Ligand mixed-valence and electrical conductivity in coordination complexes containing a redox-active phenalenol-substituted ligand

Sarah Dale, Nico M. Bonanno, Mark Pelaccia, Alan J. Lough, Atsuhiro Miyawaki, Kazuyuki Takahashi, Martin T. Lemaire

Dalton Transactions · 2019 · 11 citations · 37 references

DOI

Concepts

Abstract

Neutral Fe<sup>3+</sup> and Co<sup>3+</sup> complexes are reported featuring mixed-valent open- and closed-shell ligands, low energy IVCT bands and electrical conductivity.

References

37

Strong exchange and magnetic blocking in N23−-radical-bridged lanthanide complexes

Jeffrey D. Rinehart, Ming Fang, William J. Evans et al. · Nature Chemistry · 2011 · 1.1K citations

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A N<sub>2</sub><sup>3–</sup> Radical-Bridged Terbium Complex Exhibiting Magnetic Hysteresis at 14 K

Jeffrey D. Rinehart, Ming Fang, William J. Evans et al. · Journal of the American Chemical Society · 2011 · 1K citations

, , +17

Radical ligand-containing single-molecule magnets

Selvan Demir, Ie‐Rang Jeon, Jeffrey R. Long et al. · Coordination Chemistry Reviews · 2014 · 614 citations · Full text

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Electronic Conductivity, Ferrimagnetic Ordering, and Reductive Insertion Mediated by Organic Mixed-Valence in a Ferric Semiquinoid Metal–Organic Framework

Lucy E. Darago, Michael L. Aubrey, Chung-Jui Yu et al. · Journal of the American Chemical Society · 2015 · 397 citations · Full text

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Exploiting redox activity in metal–organic frameworks: concepts, trends and perspectives

Deanna M. D’Alessandro · Chemical Communications · 2016 · 355 citations · Full text

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