Off-resonant photoacoustic spectroscopy for analysis of multicomponent gas mixtures at high concentrations using broadband vibrational overtones of individual gas species

Abstract

The broadband photoacoustic spectroscopy (PAS) technique is proposed and demonstrated for measurement of CH₄, CO₂, and H₂O vapor in the 1.6 to 2.0 μm wavelength region. The wide spectrum of a supercontinuum light source is used to cover broadband absorption bands of multiple gas species. This sensor works in the off-resonant frequency of the designed photoacoustic cell and exhibits a wide concentration measurement range of parts per billion by volume (ppb-v) to 100%. The PAS sensor is further tested in real time by measuring the concentration of CO₂, CH₄, and H₂O vapor in biogas plants.