Phosphine-catalyzed fixation of CO₂ with γ-hydroxyl alkynone under ambient temperature and pressure: kinetic resolution and further conversion

Abstract

Phosphine-catalyzed fixation of CO₂ with γ-hydroxyl alkynone under ambient temperature and pressure was achieved and the first example of chiral phosphine catalyzed kinetic resolution of propargyl alcohols <italic>via</italic> carbon dioxide fixation was demonstrated.