ChemElectroChem · 2019 · 218 citations · 218 references
Natural SciencesChemical EngineeringChemistryElectrochemical EngineeringElectrochemistryOrganic ChemistryElectrochemical CellsElectrochemical SynthesisElectrolysis ProcessesElectrolytic CellsOrganic SynthesisRadical ReactionsAnodic SynthesisComplex Molecule SynthesisElectrochemical ConversionElectrochemical Coupling ReactionsElectrochemical Reaction MechanismsFormation Of Complex Organic MoleculesRedox-mediated SystemsSustainable Technology Development
Abstract Organic electrosynthesis is an enabling and sustainable technology, which constitutes a rapidly expanding field of research. Electrochemical approaches serve as convenient and green alternatives to stoichiometric and toxic chemical redox agents. Electrosynthesis constitutes a promising platform for harnessing the unique reactivity profiles of radical intermediates, expediting the development of new reaction manifolds. This Review highlights both anodic and cathodic methods for the construction of various kinds of complex molecules.
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Photoredox Catalysis in Organic Chemistry
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Scalable and sustainable electrochemical allylic C–H oxidation
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