Concepedia

An exceptionally stable core–shell MOF/COF bifunctional catalyst for a highly efficient cascade deacetalization–Knoevenagel condensation reaction

Ming‐Liang Gao, Mei-Hong Qi, Lin Liu, Zheng‐Bo Han

Chemical Communications · 2019 · 147 citations · 24 references

DOI

Concepts

Abstract

A novel strategy has been developed to construct a highly stable core-shell MOF@COF (PCN-222-Co@TpPa-1) bifunctional catalyst through strong π-π stacking interaction. This hybrid material with spatially isolated antagonistic acid-base sites can effectively catalyze the deacetalization-Knoevenagel condensation cascade reaction.

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