Low-dimensional non-toxic A<sub>3</sub>Bi<sub>2</sub>X<sub>9</sub> compounds synthesized by a dry mechanochemical route with tunable visible photoluminescence at room temperature

Yousra El Ajjouri, Vladimir S. Chirvony, Natalia V. Vassilyeva, Michele Sessolo, Francisco Palazón, Henk J. Bolink

Journal of Materials Chemistry C · 2019 · 51 citations · 29 references

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Abstract

We have synthesized fifteen inorganic and hybrid organic–inorganic non-toxic A<sub>3</sub>Bi<sub>2</sub>X<sub>9</sub> compounds (A = K<sup>+</sup>, Rb<sup>+</sup>, Cs<sup>+</sup>, CH<sub>3</sub>NH<sub>3</sub><sup>+</sup> and HC(NH<sub>2</sub>)<sub>2</sub><sup>+</sup>; X = I<sup>−</sup>, Br<sup>−</sup>, Cl<sup>−</sup>) through dry mechanochemistry.

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