Reversible Modulated Upconversion Luminescence of MoO₃:Yb³⁺,Er³⁺ Thermochromic Phosphor for Switching Devices

Abstract

Reversible modulation of upconversion luminescence induced by the external field stimuli exhibits potential applications in various fields, such as photoswitches, optical sensing, and optical memory devices. Herein, a new MoO₃:Yb³⁺,Er³⁺ thermochromic phosphor was synthesized via a high-temperature solid-state method, and the reversible color modification of the MoO₃:Yb³⁺,Er³⁺ phosphor was obtained by alternating the sintering conditions either in a reducing atmosphere or in air. The color of the MoO₃:Yb³⁺,Er³⁺ phosphor changed from light-yellow to blue under sintering in the reducing atmosphere and returned back after sintering again in air. The influence of reversible thermochromism on the upconversion luminescence of MoO₃:Yb³⁺,Er³⁺ phosphor was investigated. The MoO₃:Yb³⁺,Er³⁺ phosphor prepared in air exhibited visible upconversion luminescence, while the MoO₃:Yb³⁺,Er³⁺ phosphor has no upconversion luminescence after sintering in the reducing atmosphere. This up-conversion luminescence modulation shows excellent reproducibility after several cycles. The thermochromic MoO₃:Yb³⁺,Er³⁺ phosphor with reversible modulated upconversion luminescence shows great potential for practical applications in optical switches and optoelectronic multifunctional devices.